CH-222 / 2 crédits

Enseignant: Queen Wendy Lee

Langue: Anglais


Summary

Fundamental knowledge of coordination compounds.

Content

Learning Outcomes

By the end of the course, the student must be able to:

  • Recall typical ligands; name typical coordination compounds and describe their geometryJudge the existence of isomers and draw such isomers; Calculate the oxidation states of metals and the number of d electrons.
  • Apply soft-hard acid-base theory to predict the stability of complexes; interpret chelate effect; determine the relative stability of complexes according to structural factors.
  • Deduce the crystal field splitting diagram for octahedral, tetrahedral, and square planar complexes; decide the electronic configuration. Generate the ligand field diagram for octahedral complexes.
  • Decide if a complex is high spin or low spin using ligand field theory; understand and explain the spectrochemical series.
  • Estimate the spin-only magnetic moment of complexes according to ligand field theory; Determine whether an electronic transition is allowed and the intensity of such transition.

Assessment methods

1 compulsory test during the semester.

Final grade: 30% for test + 70% for final written exam

Supervision

Office hours Yes
Assistants Yes
Forum Yes

Dans les plans d'études

  • Semestre: Printemps
  • Forme de l'examen: Pendant le semestre (session d'été)
  • Matière examinée: Coordination chemistry
  • Cours: 2 Heure(s) hebdo x 14 semaines

Semaine de référence

 LuMaMeJeVe
8-9     
9-10     
10-11     
11-12     
12-13     
13-14     
14-15  MED01418  
15-16    
16-17     
17-18     
18-19     
19-20     
20-21     
21-22     

Mercredi, 14h - 16h: Cours MED01418

Cours connexes

Résultats de graphsearch.epfl.ch.